[Berion]

RTFM

Usage (Windows)
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Select 'Demultiplex' or 'Multiplex' from the main screen, and you will be taken to a screen to fill in the name of the source file(s) and destination file(s).

For demultiplexing, just hit start. If all goes ok, you will get a M2V (MPEG2 Video) file, and a WAV (Audio) file. In some cases you may find you get multiple WAV files (often ending in '-Alt1', '-Alt2', etc) - these are alternate sound streams, often used in multilingual games.

For multiplexing, you will have a few additional options:
'Use Sound Compression (ADPCM)' - For games that support ADPCM, it will compress the audio.
'Sound Stream Number' - Generally, most games will use stream 0 for an audio track. However, some games that have multilingual support will use streams 1 or higher for alternate language soundtracks. You will know this is the case if demultiplexing produces filenames that end with '-Alt#', where # is the stream number.
'Use Custom Profile' - In some cases, the PSS format used by a particular game may be radically different than normal. This option tells PSS Plex to handle the multiplex to a game's custom requirements. Currently the only option available here is for Zone of the Enders (details on this option are in the tutorial doc).

A tutorial is provided with this distribution to step you through creating DVD-rips with PSS files, for a few different games.